Development of a Fabrication Technology for Ultra-Thin Silicon Solar Cells
DOI:
https://doi.org/10.52825/siliconpv.v4i.3450Keywords:
Ultra-Thin Silicon, Optical Absorption, Bulk Recombination, Thickness, EfficiencyAbstract
Reducing the thickness of crystalline silicon solar cells is a crucial strategy for decreasing manufacturing costs and increasing mechanical flexibility. However, thinning the substrate fundamentally alters the optical and electrical behavior of the device. This study presents the analysis of the inherent trade-offs between optical absorption and internal carrier recombination in ultra-thin p-type silicon solar cells. To physically demonstrate these optical changes, standard n-type c-Si wafers were progressively thinned down by alkaline chemical etching achieving ultra-thin substrates of 70 μm, 50 μm, and 26 μm. A visual, rapid-assessment procedure utilizing a broad-spectrum white light source confirmed the filtering effect, demonstrating high transparency to red wavelengths at ultra-thinness. Reducing the cell thickness from the 150 μm to a 70 μm the effective absorption is limit to 955 nm. This leads to a loss in the absorption of higher-energy infrared photons, directly causing a drop in Jsc. Conversely, simulations reveal that this reduction in bulk silicon volume significantly decreases internal carrier recombination thereby driving an increase in Voc. The key challenge now lies in adapting industrial manufacturing equipment to realistically enable the large‑scale production of ultra-thin and flexible solar cells with low breakage rates.
Downloads
References
[1] Z. Liu, S. E. Sofia, H. S. Laine, M. Woodhouse, S. Wieghold, I. M. Peters and T. Buonassisi, "Revisiting Thin Silicon for Photovoltaics: a Technoeconomic Perspective," Energy Environ. Sci., vol. 13, pp. 12-23, 2020, doi: https/doi.org/10.1039/c9ee02452b. DOI: https://doi.org/10.1039/C9EE02452B
[2] K. A. Münzer, K. T. Holdermann, R. E. Schlosser and S. Sterk, "Thin Monocrystalline Silicon Solar Cells," IEEE Trans. Electron Devices, vol. 46, no. 10, pp. 2055-2061, Oct. 1999, doi: https/doi.org/10.1109/16.791996. DOI: https://doi.org/10.1109/16.791996
[3] J. C. Jimeno, V. Rodriguez, J. R. Gutiérrez, and F. Recart, "Very Low Thickness Monocrystalline Silicon Solar Cells," 16th EU PVSEC, May 2000, pp 1-4.
[4] T. Matsutani, T. Saga, H. Ueyama, Y. Hagihara, T. Hirano and A. Suzuki, “Ultra-thin Silicon Solar Cells for Space Application”, Jpn J. Appl. Phys, vol. 21, no S2, pp. 23-26, 1982, doi: https/doi.org/10.7567/JJAPS.21S2. DOI: https://doi.org/10.7567/JJAPS.21S2.23
[5] E. Cereda, J. Barredo-Egusquiza, J. R. Gutiérrez and J. C. Jimeno,“Mechanical Stability in Crystalline Silicon Solar Cells”, 25th EU PVSEC, pp. 1665-1668, September 2010.
[6] B. Terheiden et al, "Manufacturing 100-µm-thick Silicon Solar Cells with Efficiencies Greater than 20% in a Pilot Production Line," Phys. Status Solidi A, vol. 212, no. 1, pp. 13-24, 2015, doi: https/doi.org/10.1002/pssa.201431241. DOI: https://doi.org/10.1002/pssa.201431241
[7] Wenzhu Liu et al, “Flexible Solar Cells Based on Foldable Silicon Wafers with Blunted Edges”, Nature, Vol 617, pp. 717-738, May 2023, doi: https://doi.org/10.1038/s41586-023-05921-z. DOI: https://doi.org/10.1038/s41586-023-05921-z
[8] T. Wu, Z. Liu, H. Lin, P. Gao and W. Shen, “Free-standing Ultra-thin Silicon Wafers and Solar Cells through Edges Reinforcement“, Nature Communications, Apr. 2024, doi: https://doi.org/10.1038/s41467-024-48290-5. DOI: https://doi.org/10.1038/s41467-024-48290-5
[9] M. A. Green and M. J. Keevers, “Optical Properties of Intrinsic Silicon at 300 K”, Prog. Photovolt.: Res. Appl., vol. 3, pp. 189-192, 1995. DOI: https://doi.org/10.1002/pip.4670030303
[10] K. R. McIntosh, M. D. Abbott, and B. A. Sudbury, PV Lighthouse website of online resources for photovoltaic (PV) engineers and scientists” https://www.pvlighthouse.com.au/ (visited on February 2026).
[11] R. Saive, “Light Trapping in Thin Silicon Solar Cells: A Review on Fundamentals and Technologies”, Prog. Photovolt. Res. Appl., vol. 29, pp. 1125–1137, May 2021, doi: https/doi.org/10.1002/pip.3440. DOI: https://doi.org/10.1002/pip.3440
[12] D. A. Clugston and P. A. Basore, “PC1D version 5: 32-bit Solar Cell Modeling on Personal Computers”, 26th IEEE PVSC, pp. 207-210, Sept. 1997, doi: https/doi.org/10.1109/PVSC.1997.654065. DOI: https://doi.org/10.1109/PVSC.1997.654065
[13] ITRPV 2023 Results, p. 17, May 2024.
[14] S. W. Glunz, J. Benick, D. Biro, M. Bivour, M. Hermle, D. Pysch, M. Rauer, C. Reichel, A. Richter, M. Rüdiger, C. Schmiga, D. Suwito, A. Wolf, R. Preu, “n-type Silicon – Enabling Efficiencies > 20% in Industrial Production”, 35th IEEE PVSC, pp. 000050-000056, Jun. 2010, doiI: https/doi.org/10.1109/PVSC.2010.5614203. DOI: https://doi.org/10.1109/PVSC.2010.5614203
[15] P. J. Cousins, D. D. Smith, H-C. Luan, J. Manning, T. D. Dennis, A. Waldhauer, K. E. Wilson, G. Harley and W. P. Mulligan, “Generation 3: Improved Performance at Lower Cost”, 35th IEEE PVSC, pp. 275-278, Jul. 2010, doi: https/doi.org/10.1109/PVSC.2010.5615850 DOI: https://doi.org/10.1109/PVSC.2010.5615850
[16] L. Ning, L. Song and J. Zhang, “Research Progress of Light and Elevated Temperature-Induced Degradation in Si Solar Cells: A Review”, J. Alloys Compd., vol. 912, pp. 165120, Apr. 2022, doi: https://doi.org/10.1016/j.jallcom.2022.165120. DOI: https://doi.org/10.1016/j.jallcom.2022.165120
Published
How to Cite
Conference Proceedings Volume
Section
License
Copyright (c) 2026 Álvaro Briones-Garrachón, Mario Cruz-Giménez, Aloña Otaegi, Vanesa Fano, Eneko Cereceda, Eneko Ortega, Nekane Azkona, Federico Recart, Rubén Gutiérrez, Juan Carlos Jimeno

This work is licensed under a Creative Commons Attribution 4.0 International License.
Accepted 2026-07-02
Published 2026-09-04
Funding data
-
Ministerio de Ciencia e Innovación
Grant numbers MCIU-O23/P45;PID2023-148369OB-C42