Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners





Hydrogen permeation, Aluminosilicate glasses, Hydrogen storage tank, Glass liner


The permeation of hydrogen gas was studied in meta-aluminous (tectosilicate) glass powders of Li2O×Al2O3×SiO2 (LAS), Na2O×Al2O3×SiO2 (NAS) and MgO×Al2O3×SiO2 (MAS) systems by pressure loading and vacuum extraction in the temperatures range 210–310 °C. With this method, both the solubility S and the diffusivity D were determined, while the permeability was given by the product SD. For all glasses, S was found to decrease with temperature, while D increased. Since the activation energy of diffusion of H2 molecules exceeded that of dissolution, permeation increased slightly with temperature. When extrapolated to standard conditions (25 °C), the permeability of tectosilicate glasses was found to be only 10-22–10-24 mol H2 (m s Pa)-1, which is 8–10 magnitudes lower than most polymers. Thin glass liners of these compositions are expected to be the most effective barrier for tanks of pressurised hydrogen.


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How to Cite

Reinsch, S., Welter, T., Müller, R., & Deubener, J. (2023). Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners. Glass Europe, 1, 1–11. https://doi.org/10.52825/glass-europe.v1i.425
Received 2023-04-30
Accepted 2023-06-07
Published 2023-06-26

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