Approaches to Reduce the Impact of Edge Recombination in Si Lifetime Samples With Emitter
DOI:
https://doi.org/10.52825/siliconpv.v3i.2700Keywords:
Edge Recombination, Injection-Dependent Effective Lifetime, Edge PassivationAbstract
The injection-dependent effective excess carrier lifetime is an important quantity to describe recombination characteristics in silicon. When measured with the photo-conductance decay technique it is known that for specific sample structures and sizes edge recombination can strongly affect the measured injection-dependent lifetime. Especially in lifetime samples involving an (induced) pn-junction edge recombination can become a dominant effect limiting lifetime towards low injection. We present different approaches to structure samples in order to suppress the detrimental effect of edge recombination on lifetime at low injection.
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[1] L.E. Black and D.H. Macdonald, "Accounting for the dependence of coil sensitivity on sample thickness and lift-off in inductively coupled photoconductance measurements", IEEE J. Photovolt., vol.9, no.6, pp. 1563-1574, Nov., 2019, doi: https://doi.org/10.1109/jphotov.2019.2942484
[2] B. Veith, T. Ohrdes, F. Werner, R. Brendel, P.P. Altermatt, N. Harder, and J. Schmidt, "Injection dependence of the effective lifetime of n-type Si passivated by Al2O3: An edge effect?", Sol. Energy Mater. Sol. Cells, vol.120, pp. 436-440, Jan., 2014, doi: https://doi.org/10.1016/j.solmat.2013.06.049
[3] M. Kessler, T. Ohrdes, P.P. Altermatt, and R. Brendel, "The effect of sample edge recombination on the averaged injection-dependent carrier lifetime in silicon", J. Appl. Phys., vol. 111, no. 5, 054508, Mar., 2012, doi: https://doi.org/10.1063/1.3691230
[4] R. Basnet, D. Yan, P. Phang, T. Truong, D. Kang, H. Shen, and D. Macdonald, “Understanding the strong apparent injection dependence of carrier lifetimes in doped polycrystalline silicon passivated wafers”, Sol. RRL, vol.8, no.12, 2400087, Jun., 2024, doi: https://doi.org/10.1002/solr.202400087
[5] R.A. Sinton, P.J. Verlinden, R.M. Swanson, R.A. Crane, K. Wickham, and J. Perkins, „Improvements in silicon backside-contact solar cells for high-value one-sun applications”, in Proc. of the 13th European Photovoltaic Solar Energy Conference 1995, pp. 1586-1589
[6] K.R. McIntosh, and C.B. Honsberg, “The influence of edge recombination on a solar cell’s IV curve”, in Proc. of the 16th European Photovoltaic Solar Energy Conference 2000, pp. 1651-1654
[7] P. Altermatt, G. Heiser, and M.A. Green, “Numerical quantification and minimization of perimeter losses in high-efficiency silicon solar cells”, Prog. Photovolt: Res. Appl., vol.4, no.5, pp. 355-367, Sep., 1996, doi: https://doi.org/10.1002/(SICI)1099-159X(199609/10)4:5<355::AID-PIP145>3.0.CO;2-X
[8] S. Glunz, J. Dicker, M. Esterle, M. Hermle, J. Isenberg, F.J. Kamerewerd, J. Knobloch, D. Kray, A. Leimenstoll, F. Lutz, D. Oßwald, R. Preu, S. Rein, E. Schäffer, C. Schetter, H. Schmidhuber, H. Schmidt, M. Steuder, C. Vorgrimler, and G. Willeke, “High-efficiency silicon solar cells for low-illumination applications”, in Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference 2002, pp. 440-453, doi: https://doi.org/10.1109/PVSC.2002.1190556
[9] K. Rühle, M.K. Juhl, M.D. Abbott, L.M. Reindl, and M. Kasemann, “Impact of edge recombination in small-area solar cells with emitter windows”, IEEE J. Photovolt., vol.5, no.4, pp. 1067-1073, Jul., 2015, doi: https://doi.org/10.1109/jphotov.2015.2434597
[10] P. Baliozian, M. Al-Akash, E. Lohmüller, A. Richter, T. Fellmeth, A. Münzer, N. Wöhrle, P. Saint-Cast, H. Stolzenburg, A. Spribille, and R. Preu, “Postmetallization “Passivated Edge Technology” for separated silicon solar cells”, IEEE J. Photovolt., vol.10, no.2, pp. 390-397, Mar., 2020, doi: https://doi.org/10.1109/JPHOTOV.2019.2959946
[11] B. Hoex, S.B.S. Heil, E. Langereis, M.C.M. van de Sanden, and W.M.M. Kessels, “Ultralow surface recombination of c-Si substrates passivated by plasma-assisted atomic layer deposited Al2O3”, Appl. Phys. Lett., vol.89, no.4, 042112, Jul., 2006, doi: https://doi.org/10.1063/1.2240736
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Copyright (c) 2025 David Bäurle, Axel Herguth, Giso Hahn

This work is licensed under a Creative Commons Attribution 4.0 International License.
Accepted 2025-07-14
Published 2025-12-17
Funding data
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Bundesministerium für Wirtschaft und Klimaschutz
Grant numbers FKZ 020E-100600896