Two-Step Thermochemical Conversion of CO2 Using a Novel Nd1-xSrxMnO3 Perovskite
DOI:
https://doi.org/10.52825/solarpaces.v3i.2384Keywords:
Thermochemical Conversion, CO2 Splitting, Perovskites, Neodymium-ManganiteAbstract
A two-step thermochemical splitting process of doped and undoped neodymium-based manganite perovskites was investigated using thermogravimetric analysis. The samples were synthesized using a modified Pechini method and characterized by XRD, SEM and EDS analysis before redox testing. The results showed that 40% Sr-doped Nd0.6Sr0.4MnO3 outperformed the other samples, achieving 103.7 µmol-O2/g during thermal reduction and 189.2 µmol-CO/g during thermal oxidation, with a re-oxidation yield of 91.2%.
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References
[1] L. Fu et al., “Research progress on CO2 capture and utilization technology,” Dec. 01, 2022, Elsevier Ltd. doi: 10.1016/j.jcou.2022.102260.
[2] C. F. Heuberger, I. Staffell, N. Shah, and N. Mac Dowell, “Quantifying the value of CCS for the future electricity system,” Energy Environ Sci, vol. 9, no. 8, pp. 2497–2510, Aug. 2016, doi: 10.1039/c6ee01120a.
[3] X. Sun, S. Jiang, H. Huang, H. Li, B. Jia, and T. Ma, “Solar Energy Catalysis,” Jul. 18, 2022, John Wiley and Sons Inc. doi: 10.1002/anie.202204880.
[4] U. Pelay, L. Luo, Y. Fan, D. Stitou, and M. Rood, “Thermal energy storage systems for concentrated solar power plants,” 2017, Elsevier Ltd. doi: 10.1016/j.rser.2017.03.139.
[5] P. Denholm, J. C. King, C. F. Kutcher, and P. P. H. Wilson, “Decarbonizing the electric sector: Combining renewable and nuclear energy using thermal storage,” Energy Policy, vol. 44, pp. 301–311, May 2012, doi: 10.1016/j.enpol.2012.01.055.
[6] G. Alva, Y. Lin, and G. Fang, “An overview of thermal energy storage systems,” Feb. 01, 2018, Elsevier Ltd. doi: 10.1016/j.energy.2017.12.037.
[7] L. F. Cabeza, A. Solé, and C. Barreneche, “Review on sorption materials and technolo-gies for heat pumps and thermal energy storage,” Renew Energy, vol. 110, pp. 3–39, 2017, doi: 10.1016/j.renene.2016.09.059.
[8] A. H. Abedin and M. A. Rosen, “A Critical Review of Thermochemical Energy Storage Systems,” 2011.
[9] T. O. L. Sunde, T. Grande, and M. A. Einarsrud, “Modified pechini synthesis of oxide powders and thin films,” in Handbook of Sol-Gel Science and Technology: Processing, Characterization and Applications, Springer International Publishing, 2018, pp. 1089–1118. doi: 10.1007/978-3-319-32101-1_130.
[10] J. Jouannaux, A. Haeussler, M. Drobek, A. Ayral, S. Abanades, and A. Julbe, “Lantha-num manganite perovskite ceramic powders for CO2 splitting: Influence of Pechini syn-thesis parameters on sinterability and reactivity,” Ceram Int, vol. 45, no. 12, pp. 15636–15648, Aug. 2019, doi: 10.1016/j.ceramint.2019.05.075.
[11] G. Takalkar et al., “Thermochemical splitting of CO2 using solution combustion synthe-sized lanthanum–strontium–manganese perovskites,” Fuel, vol. 285, Feb. 2021, doi: 10.1016/j.fuel.2020.119154.
[12] K. Gao et al., “Remarkable solar thermochemical CO2 splitting performances based on Ce- and Al-doped SrMnO3 perovskites,” Sustain Energy Fuels, vol. 7, no. 4, pp. 1027–1040, Jan. 2023, doi: 10.1039/d2se01496c.
[13] Z. Chen et al., “Sr- and Co-doped LaGaO3-δ with high O2 and H2 yields in solar thermo-chemical water splitting,” J Mater Chem A Mater, vol. 7, no. 11, pp. 6099–6112, 2019, doi: 10.1039/c8ta11957k.
[14] L. Wang et al., “Experimental study on the high performance of Zr doped LaCoO3 for solar thermochemical CO production,” Chemical Engineering Journal, vol. 389, Jun. 2020, doi: 10.1016/j.cej.2020.124426.
[15] X. Liu et al., “Ca- And Ga-Doped LaMnO3for Solar Thermochemical CO2Splitting with High Fuel Yield and Cycle Stability,” ACS Appl Energy Mater, vol. 4, no. 9, pp. 9000–9012, Sep. 2021, doi: 10.1021/acsaem.1c01274.
[16] G. Takalkar et al., “Thermochemical splitting of CO2 using solution combustion synthe-sized LaMO3 (where, M = Co, Fe, Mn, Ni, Al, Cr, Sr),” Appl Surf Sci, vol. 509, Apr. 2020, doi: 10.1016/j.apsusc.2019.144908.
[17] B. Chen, H. Kildahl, H. Yang, Y. Ding, L. Tong, and L. Wang, “Thermochemical splitting of CO2 on perovskites for CO production – A review,” Mar. 01, 2024, Elsevier B.V. doi: 10.1016/j.jechem.2023.11.041.
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Copyright (c) 2026 Muhammad Usman, Giovanni Palmisano, Georgios Karanikolos, Stéphane Abanades, Khalid Al-Ali

This work is licensed under a Creative Commons Attribution 4.0 International License.
Accepted 2025-05-16
Published 2026-01-26
Funding data
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Khalifa University of Science, Technology and Research
Grant numbers RC2-2019-007